CFCXM - CARBON DIOXIDE,11042

Product Identification

Product ID:CARBON DIOXIDE,11042
MSDS Date:07/01/1986
FSC:4730
NIIN:01-365-6916
Kit Part:Y
MSDS Number: CFCXM

Responsible Party
UNION CARBIDE CORP LINDE DIV
39 OLD RIDGEBURY RD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-UCC-HELP (800-822-4357)

Info Phone: 203-744-3487

Cage: 36346

Contractor
UNION CARBIDE CORP LINDE DIV
DANBURY, CT 06817-0001 US

Telephone: 800-822-4357; 304-744-3487

Cage: 36346

Ingredients

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 100%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;96

Hazards

LD50 LC50 Mixture:TLV IS 5000 PPM.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:LUNGS, CNS, EYES, SKIN.
ACUTE- CONTACT WITH LIQUID CAN CAUSE EYE AND SKIN FROSTBITE. GAS
MAY CAUSE EYE IRRITATION. ASPHYXIANT. INHALATION MAY CAUSE
RESPIRATORY ACIDOSIS. HIGH CONCENTRATI ONS MAY CAUSE RAPID
CIRCULATORY INSUFFICIENCY LEADING TO DEATH. INGESTION IS NOT LIKLEY
(GAS). CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:FROSTBITE, EYE IRRITATION, HEADACHE,
DROWSINESS, DIZZINESS, STINGING OF THE EYES, NOSE AND THROAT,
EXCITATION, RAPID BREATHING AND HEART RATE, EXCESS SALIVATION,
SHORTNESS OF BREATH, MUSCULAR WEAKNESS , RINGING IN THE EAR,
UNCONSCIOUSNESS, COMA, NAUSEA, VOMITING, WATERY EYES (FORMATION OF
WEAK CABONIC ACID)
Medical Cond Aggravated by Exposure:PERSONNEL WITH PRE-EXISTING CHRONIC
RESPIRATORY DISEASES OR HEART DISORDERS SHOULD REFRAIN FROM
BREATHING EXCESSIVE CARBON DIOXIDE.

First Aid

First Aid:INHALATION:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEE AN
OPHTHALMOLOGIST, URGENTLY. SKIN:FLUSH WITH WARM WATER (NOT TO
EXCEED 106 F). PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES
OF OVEREXPOSURE TO CO2. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH
SELF CONTAINED BREATHING APPARATUS. ORAL:NOT LIKELY. LIQUID CAUSES
FROSTBITE.

Fire Fighting

Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CYLINDERS.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
NIOSH-APPROVED SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CARBON DIOXIDE CANNOT CATCH FIRE BUT
CYLINDERS MAY RUPTURE.

Accidental Release

Spill Release Procedures:LIQUID CARBON DIOXIDE WILL FORM SOLID CO2 (DRY
ICE) WHEN RELEASED TO ATMOSPHERIC PRESSURE. THE AREA SHOULD BE
VENTILATED. CLEAN UP PERSONNEL SHOULD WEAR SELF-CONTAINED BREATHING
APPARATUS WITH FULL FA CE MASK AND HEAVY PROTECTIVE CLOTHING.
Neutralizing Agent:NOT RELEVANT

Handling

Handling and Storage Precautions:STORE IN A COOL, WELL-VENTILATED
PLACE. DO NOT STORE ABOVE 120F. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:KEEP AWAY FROM SOURCES OF HEAT. CAUTION! CAN CAUSE
RAPID SUFFOCATION DUE TO OXYGEN DEFICIENCY. USE WITH ADEQUATE
VENTILATION. CO2 IS HEAVIER THAN AIR AND TENDS TO ACCUMULATE NEAR
THE FLOOR IN CLOSED S PACES. READ ALL LABELS INSTRUCTIONS.

Exposure Controls

Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. HOWEVER,
AIR-SUPPLIED RESPIRATORS ARE REQUIRED WHILE WORKING IN CONFINED
SPACES WITH THIS PRODUCT. THE RESPIRATORY PROTECTION USE MUST
CONFORM WITH OSHA RULES AS SPECIF IED IN 29 CFR 1910.134.
Ventilation:SUFFICIENT TO PREVENT ACCUMULATION ABOVE TLV. LOCAL EXHAUST
LOCATED NEAR THE FLOOR.
Protective Gloves:INSULATED AND COLD RESISTANT NEOPRENE
Eye Protection:SAFETY GOGGLES RECOMMENDED
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER,
INDUSTRIAL-TYPE WORK CLOTHING, SAFETY SHOES AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
KEY1:G3. THIS KIT CONSISTS OF CARBON DIOXIDE (PNI A) AND COUPLING HOSE
(PNI B), PER TECHNICAL SUPPORT AND DDSP-XP.

Chemical Properties

HCC:G3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:-109F SUBLI
Vapor Pres:43671 @70F
Vapor Density:1.52
Spec Gravity:GAS
pH:ACIDIC
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT (GAS)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS, ODORLESS GAS
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, ALKALINE EARTH METALS, CHROMIUM
Stability Condition to Avoid:OVERHEATING CYLINDERS (125F/52C)
Hazardous Decomposition Products:OXYGEN AND HIGHLY TOXIC CARBON
MONOXIDE

Disposal

Waste Disposal Methods:SLOWLY RELEASE INTO ATMOSPHERE OUTDOORS.
DISPOSAL SHOULD BE IN COMPLIANCE WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS. DEFECTIVE CYLINDERS SHOULD BE TAGGED TO INDICATE A
DEFECT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.